![]() It also became an important oil for Ayurvedic medicine. Derived from the seeds of the castor bean plant, ancient Egyptians used castor oil to treat eye, skin, and hair conditions, as well as headaches. Its earliest mention was in the 6,000-year-old Papyrus Ebers, an ancient Egyptian scroll of herbal medicine. Take a teaspoon, and you are good! Some parents threatened a spoonful as “punishment.” Ah, the dreaded castor oil! This was so popular and common that it made its way into TV shows - from "Tom and Jerry" to "The Little Rascals."Įven before the modern era, people loved castor oil. Sci.Not so long ago, moms everywhere used castor oil as a cure-all for many ailments, from stomach pain to fever to its most famous use - easing constipation. Zhang, J., Tang, J.J., Zhang, J.X.: Polyols prepared from ring-opening epoxidized soybean oil by a castor oil-based fatty diol. ![]() Zajcew, M.: The hydrogenation of fatty oils with palladium catalyst. Yusuf, A., Mamza, P., Ahmed, A., Agunwa, U.: Extraction and characterization of castor seed oil From wild Ricinus communis Linn. Meller, E., Green, U., Aizenshtat, Z., Sasson, Y.: Catalytic deoxygenation of castor oil over Pd/C for the production of cost effective biofuel. William Andrew, Oxford (2015)Īlwaseem, H., Donahue, C.J., Marincean, S.: Catalytic transfer hydrogenation of castor oil. Madbouly, S., Zhang, C., Kessler, M.R.: Bio-based plant oil polymers and composites. Šmidovnik, A., Štimac, A., Kobe, J.: Catalytic transfer hydrogenation of soybean oil. Shrirame, H.Y., Panwar, N., Bamniya, B.: Castor oil hydrogenation by a catalytic hydrogen transfer system using limonene as hydrogen donor. Martinelli, M., de Souza Schneider, R.D., Baldissarelli, V.Z., von Holleben, M.L., Caramão, E.B.: Glycerol as solvent and hydrogen donor in transfer hydrogenation-dehydrogenation reactions. Wolfson, A., Dlugy, C., Shotland, Y., Tavor, D.: Catalytic transfer hydrogenations of olefins in glycerol. Tavor, D., Popov, S., Dlugy, C., Wolfson, A.: Catalytic transfer hydrogenations of olefins in glycerol. Int J Adv Sci Eng Inf Technol 7, 843–849 (2017) Wiley, Hoboken (2008)įitri, H., Tatang, H.S., Subagjo, Tirto, P.: Low temperature catalytic-transfer hydrogenation of candlenut oil. Solomons, T.W.G., Fryhle, C.B.: Organic Chemistry, 10th edn. Salimon, J., Noor, D.A.M., Nazrizawati, A., Firdaus, M.M., Noraishah, A.: Fatty Acid composition and physicochemical properties of malaysian castor bean Ricinus communis L. Peña, R., Romero, R., Martínez, S.L., Ramos, M.J., Martínez, A., Natividad, R.: Transesterification of castor oil: effect of catalyst and co-solvent. Gilbert, E.: The unique chemistry of castor oil. Patel, V.R., Dumancas, G.G., Viswanath, L.C.K., Maples, R., Subong, B.J.J.: Castor oil: properties, uses, and optimization of processing parameters in commercial production. Mutlu, H., Meier, M.A.: Castor oil as a renewable resource for the chemical industry. Mubofu, E.B.: Castor oil as a potential renewable resource for the production of functional materials. Therefore, it was proven that, the glycerol can be used as the hydrogen donor for the castor oil for a catalytic transfer hydrogenation reaction. The melting point of the hydrogenated castor oil is 65 ☌ and the melting point of castor oil is − 7 ☌. The increment in melting point value and the absence of C=C peak (1655.79 cm −1) from FTIR spectrum shows that the catalytic transfer hydrogenation successfully occurred. The result from FTIR along with the melting point shows the formation of hydrogenated castor oil from this reaction. A direct heating apparatus connected with a reflux system was used for this experiment. To prove whether glycerol can be one of the hydrogen donors like limonene that is commonly used, the research started by using pure glycerol as the hydrogen donor and as a control to determine the protocol. The reaction occurred at the reaction temperature of 178 ☌ for an hour. A catalytic transfer hydrogenation of castor oil using glycerol-based is a process of adding hydrogen to the castor oil to produce hydrogenated castor oil with the addition of 10% Pd/C as the catalyst and glycerol as a hydrogen donor.
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The standard setup is at 540p with a 30 frames-per-second standard frame rate. You should also take a look at your setting panel to adjust the streaming quality. Users should make sure that their PS4 is set to recognize your device. ![]() In less than a minute, you should see a pop up with the familiar PS4 UI. Once you have the software installed on your device, you need to connect a Dual Shock 4 via USB. You may need to provide administrator permissions to delete the file.Setting up your PS4 Remote Play is easy. Once you have located the file, you can delete it by right-clicking on it and selecting "Delete" from the context menu. Alternatively, you can search for the file in the Windows Explorer. To do this, open the file location of stress-reducer-desktop-destroyer.exe by right-clicking on it in the Task Manager and selecting "Open file location" from the context menu. Step 3: Delete stress-reducer-desktop-destroyer.exeĪfter ending the process, you can delete stress-reducer-desktop-destroyer.exe from your computer. This will stop the stress-reducer-desktop-destroyer.exe process. Once you find it, right-click on it and select "End task" from the context menu. In the Task Manager, go to the "Processes" tab and locate stress-reducer-desktop-destroyer.exe. Step 2: End the stress-reducer-desktop-destroyer.exe Process Alternatively, you can press the "Ctrl + Shift + Esc" keys together to open the Task Manager directly. To do this, right-click on the taskbar and select "Task Manager" from the context menu. The first step is to open the Task Manager. ![]() How to remove stress-reducer-desktop-destroyer.exe file from my computer: Perform a system restore: If the issue occurred recently, you may be able to resolve it by performing a system restore to a previous point in time when the system was working correctly. Reinstall the application: If the issue is related to a particular application that uses the unknown product, try reinstalling the application to see if that resolves the issue. Repair Windows registry: Use a reputable registry repair tool to scan and repair any registry errors that may be affecting the stress-reducer-desktop-destroyer.exe file. ![]() Update your drivers: Ensure that your system drivers are up-to-date, particularly for your graphics and audio drivers. Update your operating system: Ensure that your operating system is up-to-date with the latest security patches and updates. Perform a malware scan: Run a full system scan using reputable anti-virus and anti-malware software to check for any infections that may be affecting the stress-reducer-desktop-destroyer.exe file. Steps to fix stress-reducer-desktop-destroyer.exe Errors: If you are experiencing issues with the stress-reducer-desktop-destroyer.exe file. 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Our qualified technicians, utilizing the most sophisticated alignment machines, will ensure your vehicle is aligned to the specifications set forth by your vehicle manufacturer. Tire rotation and balancing are other tasks that improve the longevity of your tires.ĭid you know front-end or 4-wheel alignments can be performed in as little as one hour on most vehicles? Protect your vehicle’s suspension and tires by having a wheel alignment performed on your vehicle at Automotive Super Center. Find the best Wheel Alignment near you on Yelp - see all Wheel Alignment open now. In addition, your car will drive smoother and your fuel efficiency will increase because it takes less energy for your car to keep the tires moving forward in a straight line. A wheel alignment straightens out all your tires, so your suspension and steering systems are more equipped to control them and keep you safe on the road. ![]() Wheel alignment prevents many tire and suspension related issues, including premature tread wear. As a result, wheel alignment is typically for four-wheel drive cars. Front end alignment involves aligning only the front two tires while wheel alignment involves aligning all four tires. How much does a wheel alignment cost Having correctly aligned wheels is a vital part of keeping your vehicle performing at its best. Both require the same process, but they refer to the number of tires being aligned. Wheel alignment and front-end alignment are often used interchangeably by professionals. Difference Between Wheel Alignment & Front End Alignment Misaligned wheels often lead to accelerated tire wear, which can get quite costly if you. A mechanic will place a specialized machine on each tire and straighten it out to match the manufacturer’s specifications. Wheel alignment issues are caused by worn suspension components. If your vehicle veers to the right or left, your tires are out of position. This includes a full inspection of your suspension and steering. You can determine if you need a wheel alignment by driving on a straight road with your steering wheel centered. Especially in these places, the price only ranges from 50-100 for wheel alignment. Over time, your wheels become jolted out of position due to driving over rough terrain, hitting curbs, and running over potholes. Find your nearest Tires Plus for a wheel alignment in Florence, KY, plus all the around-the-wheel services your car needs, like tire rotation and balancing. Wheel alignment is the straightening of the wheels, so they’re back in their original factory positions. These terms can be confusing, so below is an explanation of the difference between wheel alignment and front end alignment. However, when you take your vehicle to the auto repair shop, your mechanic might discuss the need for front end alignment. Truck wheel alignment services are available at 205 TA Truck Service locations from coast to coast.Depending on the length of your driving tenure, you probably know the importance of tire maintenance tasks like tire rotation and wheel alignment. We offer a complete inventory of available parts and experienced, professional technicians ready to keep you on the road and your vehicle running smoothly. The TA Truck Service network is your alignment expert. No matter the cause, when your truck starts pulling to either side or you feel vibrations in your steering wheel, TA Truck Service can set your truck back on track. Misalignment can be caused by anything from road conditions, pot holes and bumps to driver habits. A front-end wheel alignment will deal solely with the wheels on the front of your vehicle. Proper truck wheel alignment is crucial to the safe operation of your truck. Not only does accurate wheel alignment improve gas mileage, but it also extends the life of your tires by preventing uneven wear.Īn alignment check should be part of any professional driver's regular maintenance routine, and alignment should also be checked whenever new tires are purchased. Then press Enter or Click Search, youll see search results as red mini-pins or red dots where mini-pins show the top search results for you. Improve your truck's performance with wheel alignment services. How to find front end alignment near me Open Google Maps on your computer or APP, just type an address or name of a place. A few years back, my brother was selling some downloadable audiobooks. Why Is Amazon Digital Order Pending?ĭigital products can also be stuck in bureaucratic hell of pending orders due to payment issues or prolonged verification process. It’s frustrating because your product is actually on the move and you know nothing about it until it’s almost delivered. Most of the time though, when the order is simply Pending for a few days, they’re just prepping and packing the order. Sometimes your package needs to be tossed around from one facility to another until it reaches the destination that’s the closest to the buyer. Amazon order pending verification can take up to 21 days! ![]() If the order is pending verification, it is most likely due to an issue with the buyer's credit card. Why Does Amazon Take So Long to Process Orders? Being an Amazon seller demands a lot of patience. With the rest of the issues, you just need to wait it out a bit longer. With the first two issues, you need to contact the buyer and try to resolve the situation with Amazon’s customer service. The buyer qualified for free bulk shipping so all of the items need to be gathered One of the items in the FBA order is out of stock The buyer’s credit/debit card wasn’t authorized On the other hand, a pending order might also suggest an issue with the following: You’ll forget that this problem ever happened. In most cases this Amazon order processing will end in a couple of days and your product will be sent off to a new home. What Does It Mean When an Order Is Pending?Ī pending order is sometimes just Amazon's way of explaining that your product is being prepared and processed. In order to figure it out, I did some research and here is what I found out. It happened to me as well, and shortened my life span by at least a couple of years. This is something that happens to hundreds of Amazon sellers around the world. Sounds familiar? Don’t worry, you are not alone. You get more nervous by the hour as you click on every single link you can find. Your buyer contacts you to ask what’s wrong and you have no idea. You are confronted with the infamous “Amazon Orders Pending” message. A big smile stretches across your soon-to-be-rich face as you wait for the order to come through. You’ve set up your shop, uploaded the products, and even found your first buyer. From comfortable dresses to women’s sweaters and cardigans and UGG® for men, you’ll find seasonal styles, fun finds and great deals at Zappos.Things have been going smoothly. So, go ahead-shop here for women’s, men’s and kids’ shoes, accessories and clothing. You’ll also experience the unmatched 24/7 customer service from our Customer Loyalty Team that is known for, as well as our 365-day return policy. : Seasonal Styles, Fun Finds and DealsĪs always, you’ll enjoy the high-quality service, comprehensive inventory of products and top-notch customer service that have set us apart for decades. 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Linking your Amazon Prime membership to your account is easy: just follow the directions on this page to link your accounts and take advantage of the specials and perks that are provided to Amazon Prime customers at. Zappos VIP Program and Amazon Prime Login But did you know that you can also access your Amazon Prime login at when you join our Zappos VIP Program? Link your and your Amazon Prime login account and receive special perks, upgraded free shipping and bonus points for every $1 you spend at. ![]() customers already know that we are powered by service. Explore in Teva Search Within Women SearchĪmazon Prime and : The Perfect Match ![]() You get four playable classes and everything that they need including character sheets, decks of cards, minis, and nice cardboard portraits of them.įor the price, Jaws of the Lion is packed with stuff. Finally, there are a dozen or so types of tokens, an element board, and a crap ton of different card types. In addition, there are a bunch of monster standees, and cards for them. You get a map of Gloomhaven, four books, two of which are rules and how to play, and two that are centered around the game’s 25 scenarios. So I’m just going to do a vague overview. But given the nature of the game, doing that would be spoiling a lot of surprises. In these reviews, I normally walk through all the components. The initial setup takes a while, but it’s mostly painless after that. The innards of the box come with a bunch of baggies and specific places for you to organize and store all the pieces, tokens, and cards. That the game doesn’t bite, and it’s going to walk you through taming the monster before it devours the living room table in clutter. Heck, the first thing you see when you open the box is a giant paper basically telling you not to panic. While Jaws of the Lion is a great deal smaller than the base game, you’re still going to be buried in an absolute ton of game pieces. The good news is, you might be ready for that commitment after a few dates with Jaws of the Lion…mines pickles. It aims to win you over gently, rather than dropping the 22-pound base game on your face that will demand to know your safe word. I would say that Jaws of the Lion is a cheaper, smaller entry point into the world of Gloomhaven instead. But I wouldn’t say it’s an expansion at all, very little material is cross-compatible. Jaws of the Lion is billed as a stand-alone expansion to the mega-sized base game. Gloomhaven is its own beast with separate design goals. Any attempt to do so will end up diluted. ![]() You can’t truly simulate the open-ended nature of a TTRPG in board-game form. Outside of being fantasy games where you fight monsters, they aren’t even in the same league of being similar. ![]() You can find a video version of this review on my YouTube Channel After playing Jaws of The Lion, I would like to find all these people and club them with a 600-page core rulebook for being wrong and leading me astray. I already play Pathfinder, I don’t need a cut-down board game version. I had seen people call it D&D or Pathfinder without a GM, and that meant I had no interest in it. To my great shame, I slept on Gloomhaven for the longest time. hypothyroidism), immunological, musculoskeletal (e.g. renal impairment), gastrointestinal, cardiovascular, cerebrovascular, pulmonary, endocrine (e.g. active liver disease, hepatic impairment), renal/genitourinary (e.g. Known history or presence of any clinically significant hepatic (e.g.Agree to avoid pregnancy and use medically acceptable method of contraception from screening day until 30 days after the study ends (last study procedure).Post-menopausal for a minimum of 1 year.Be surgically sterile for a minimum of 6 months. ![]() Subjects must fulfill at least one of the following: Able to perform special breathing using nebulizer correctly as per the required standard.Subjects who are non-asthmatic, defined as no clinical history of asthma, allergy or atopy.Never-smokers or former smokers who have smoked ≥ 100 cigarettes in their lifetime and have not consumed any tobacco or tobacco containing products for at least 12 months prior to screening.Agree not to have a tattoo, body piercing, or other any invasive procedure and blood donation until the end of the study. ![]()
![]() Feed Wranglerįeed Wrangler costs $19 per year, and seemed promising at first. But Feedbin is certainly a service that gives me hope for our Google Readerless future. Sometimes, though, it can feel a little slow on the Web: Marking as read takes a couple of extra beats the article preview pane can’t keep up as you’re navigating through your feed source list. Feedbin isn’t a desktop client, but it’s working hard to feel awfully close. Keyboard shortcuts let you open the current story in another tab, including an option (Shift-V) to open that tab in the background. There’s built-in Readability integration, so if a site’s RSS feed doesn’t include the complete article, you can click a button to load the rest of the story in many cases. The keyboard shortcuts are plentiful, and include excellent arrow key support, which warms my heart. Your folders become tags in Feedbin’s parlance, and there are plenty of settings to tweak how the Web app organizes and sorts your feeds. It’s the first Web service I tried that I felt I could make work. While it ostensibly works, it’s hard to recommend.įeedbin charges, too it costs $2 per month, or $20 per year. There’s decent, omnipresent keyboard control, but no current folder support, mangled timestamps, and other problems. But the open-source service’s plain-Jane interface would disappoint even a hardcore Linux-lover. That semblance of a business model goes in the pro column. I mean, if you really want to.įeedHQ, on the other hand, charges money-$12 per year. Newsify app with Feedly that offers a pleasant enough browsing experience on iOS, but leaves you without a great reading solution on your Mac. To its credit, the service does support a slew of keyboard shortcuts, handles folders well, and uses a clean layout-just one that doesn’t work for me. It doesn’t help that I’m no fan of Feedly’s interface on the Web: I basically want something that looks like NetNewsWire, and Feedly isn’t it. If Google-Google!-couldn’t figure out a way to monetize this kind of service, I’m not sure anyone can. As Google Reader’s demise gets closer, expect more apps to announce support for new services.įeedly is free. Reader supports every service mentioned above on the iPad. The iPad version) currently works with Feedbin and Fever. (BazQux clearly didn’t get the “start name with F” memo.)ĭifferent apps work with different services. Young upstartsįeedly, FeedHQ, Feedbin, Feed Wrangler, Fever, and BazQux Reader are all smaller companies looking to usurp Google Reader’s old place in our hearts and software. That may be because Google, one of the biggest big guys, just left me high and dry. In some ways, though, I’m more intrigued by the little guys entering the space. Some of the companies are huge-we’ll get to them in a bit. There are several companies aiming to replace Google Reader both as Web services and as backend APIs for third-party apps to connect to. Then click Create Archive, wait a minute or three, and click Download to grab the completed archive. Click the Choose Services tab, and then find Reader in the alphabetical list. Google Takeout, and re-enter your password if prompted. If you use an app like NetNewsWire, you can use its Export OPML options. If you haven’t exported them yet, do so before July 1 rolls around. But listen-and this is important- the time to export your Google Reader subscriptions is now. Many services can import your Google Reader subscriptions. Google may still offer the option to export your data after July 1, but there are no guarantees. Export your Google Reader data now, before July 1. An entry blacked out with the words “This record is officially closed” means that that person is still living. The house number is in the left hand column, then the number of people in the household at that time, their names, their gender, date of birth, age, marital status and occupation. The following is an example of an entry from the 1939 register: However as this is the beginning of World War Two, some family members may have been called up and some children may have been evacuated away from home and so will not be included. It is perhaps easiest to start with the censuses and registers, the most recent of which is the 1939 register. To begin, simply start by entering all the details you know about one of your relatives: their full name, where they lived, their date of birth (if known) and then you’re off! Sites such as Ancestry, FindMyPast and MyHeritage all offer a free trial period, after which a small monthly fee is to be paid depending on the amount of access you require from their databases. ![]() To fill in the gaps and to go further back in time, the easiest way to progress is via an online family research site. A tree usually takes one of two forms: either horizontal:Ĭhoose the style that seems right for you. Nevertheless, you should be able to construct a simple family tree from this information. On further investigation, it transpired they came from the West Country – Cornwall! Ask everyone in the family for their stories some may be based in truth and help with your research, others however may be a little off the mark! An example of this when asking an elderly relative about the family, one researcher (namely the one writing this guide!) was told with great certainty that her husband’s family came from Westmorland, Cumbria. This is the quickest way to begin assembling your family tree. ![]()
![]() There’s smaller bundles, in the $300 range, that will give you access to core rulebooks and campaign books. That’s enough content to fuel multiple D&D campaigns for many, many years. A charming thief and a band of unlikely adventurers undertake an epic heist to retrieve a lost relic, but things go dangerously awry when they run afoul of the wrong people.They still have a finite amount of spell slots (assuming it’s not vecna with counterspell as a legendary actions) Stay out of range.1 day ago Also a 8th lvl Warlock, assuming your eldritch blast is good, just use that and burn the litches counterspell uses. Counterspell is pretty good against counterspell. Amid all of the concerns in the D&D third party community surrounding the OGL, I've released …DISBOARD | Public Discord Server ListRepeat. Play a free solo treasure hunt in an icy haunted castle: Beyond the Vale of Madness. If anyone has any ideas that would be much appreciated. I’m also not sure where the divisions between the areas like the swamp and the causeway is. ![]() As a dm I’ve been checking every hex, but this has killed characters multiple times and it seems tedious and difficult. Dungeons & Dragons The next version of D&D is coming, and Monsters of the Multiverse is your first taste Monsters of the Multiverse is designed to be ‘backward-compatible’ with 5th edition By.Anybody know how to check encounters on “Challenge of the frog idol”. In this DnD game, the Feywild is more like some. She's chooses to forever remain in the autumn season in honor of her patron, Adelina the Autumn Queen, but her heart and soul remain stuck more like a winter Eladrin than any other. Nuala probably being the last of her bloodline before losing that Feywild connection and becoming like most elves. the DnD subreddit boasts 2.3 subscribers, making it the largest collection of Dungeons and Dragons players, DMs, and fans on the entire site. Reddit dnd Here are the subreddits you need to know about to get you started on your Dungeons and Dragons journey of knowledge and discovery: r/DnD Well, we obviously have to start big, don’t we. ![]() To connect a standalone Blu-ray player to a pc monitor is just about plug-and-play.Īssuming that your desktop has a monitor with an HDMI port, you can plug the blu ray player into your monitor with an HDMI cable and change the input settings to HDMI input on the monitor. Connect Regular Blu-Ray Player to My Computer Monitor with HDMI HDMI Input If you have enabled DLNA on your Blu-ray Player and you want to use it as a Blu-ray drive to your PC, then you can have a client on your computer, like VLC, which has the capability to perform as a DLNA client.Ģ. Is there an exception? How about connecting a DLNA Blu-ray Player to PC as an external BD driver for my Windows PC? Also, some older video cards may not support HDCP on the VGA connection. That’s not legal to decode the HDCP signal. Normally, the outputs video of your Blu-ray player will be encrypted with HDCP (High-bandwidth Digital Content Protection), while the HDMI capture device is a recording device. Because of your low-cost hardware which is not as good as a professionally made Blu-ray in encoding. That is impossible to have enough bandwidth for the AVC encoding. The bitrate of the compressed video transferred to the pc will decrease to around 100Mbs. If you intend to make a compromise and accept a compressed video with a USB HDMI capture device, you will learn a hard lesson from this.īecause the HDMI capture device you can find will do on-board AVC encoding on its own. The 4K bitrate can even go up to 20Gbs, which is beyond the ability of the USB 3.1 Gen 2 port to capture. Of course, it is possible to capture and re-display video via HDMI for the uncompressed video.īut you will need a Thunderbolt port to do the capture.īecause the data transferred via HDMI for a basic Blu-ray playing is about 4.9 gigabits per second (Gbs). Yep, these tricks are also included here. Or, assuming you have a desktop computer, you can also use an HDMI cable to connect the Blu-ray player to PC monitor if you like.įor home entertainment, you might looking for the solution to connect a DLNA enabled Blu-ray Disc player to a computer and stream media like music, video, and photos on your computer. ![]() However, if you want to try it out of curiosity, you can check the “ Feasibility Analysis of Connecting a Regular/DLNA Blu-Ray Player to PC” below and find the answer you need. The easier and more time-saving way is to get a Blu-ray computer driver and BD player or BD ripper software. If your Blu-ray player is a standalone unit that is designed to play movies discs and output to a TV screen, and you want to use it as an external BD driver for your computer, then things may become very complicated due to several technical problems. You can follow the guide here to connect and set up Blu-ray player on your computer, then play movies with BD player or ripper software. ![]() If it is a Blu-ray player that needs a drive bay to be mounted to your desktop, or a slim external Blu-ray drive using a USB cable to connect to your laptop, then the procedure of connecting Blu-ray player to pc is simple. Is it a standalone Blu-ray player (like Sony or LG) you want to use as an external disc driver for your pc, or you want to use these two devices to set up a DLNA server? Or it is just a Blu-Ray disk drive for the PC you want to mount to your computer. ![]() Well, it depends on what kind of Blu-ray player you have. “How to connect Blu-ray player to my desktop or laptop?” |